An iron catalyzed regioselective oxidation of terminal alkenes to aldehydes.
نویسندگان
چکیده
Fe(BF(4))(2)·6H(2)O with pyridine-2,6-dicarboxylic acid and PhIO can efficiently catalyze the regioselective oxidation of terminal alkene derivatives to aldehydes under mild and benign reaction conditions.
منابع مشابه
Anti-Markovnikov oxidation and hydration of terminal olefins.
Efficient syntheses of aldehydes and primary alcohols from terminal olefins are critical to the chemical laboratory and industry. Heavy emphasis has been placed on regioselective olefin functionalization in recent decades. This perspective mainly focuses on advances in the Wacker-type oxidation and tandem hydration of terminal olefins with anti-Markovnikov selectivity.
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متن کاملPalladium-assisted multicomponent cyclization of aromatic aldehydes, arylamines and terminal olefins under molecular oxygen: an assembly of 1,4-dihydropyridines.
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 44 شماره
صفحات -
تاریخ انتشار 2012